Roymech engineering encyclopedia

Ions and Cations


Ions are electrically charged atoms or molecules formed by the loss or gain of electrons. They are fundamental to chemistry, electrochemistry, and many engineering processes including corrosion, electrolysis, and material reactions.

This page explains the difference between cations and anions and provides tables of commonly used monoatomic and polyatomic ions.


Introduction

Ions are divided into two groups; cations and anions. Cations have a positive charge and are formed when atoms lose electrons. Typical cations include sodium (Na+), calcium (Ca2+), and magnesium (Mg2+). Anions have a negative charge and are formed when atoms gain electrons. Typical anions include chloride (Cl-), sulfate (SO42-), and bicarbonate (HCO3-).


Common Monatomic Cations and Anions

The table below lists commonly encountered monoatomic ions used in chemistry and engineering calculations.

Cations Anions
Symbol Name Symbol Name Symbol Name
H+hydrogen ion Hg22+mercury(I)
mercurous
H-hydride
Li+lithium ion Hg2+mercury(II) mercuric F-fluoride
Na+sodium ion Fe2+iron(II)
ferrous
Cl-chloride
K+potassium ion Fe3+iron(III)
ferric
Br-bromide
Rb+rubidium ion Pb2+lead(II)
plumbous
I-iodide
Cs+cesium ion Be2+beryllium ion O2-oxide
Pb4+lead(IV)
plumbic
Sn2+tin(II)
stannous
S2-sulfide
Mg2+magnesium ion Sn4+tin(IV)
stannic
Se2-selenide
Ca2+calcium ion Sr2+strontium ion Te2-telluride
Co2+cobalt(II)
cobaltous
Co3+cobalt(III)
cobaltic
**
Ba2+barium ion Cr2+chromium(II)
chromous
**
Ag+silver ion Cr3+chromium(III)
chromic
N3-nitride
Ra2+radium ion Al3+aluminum ion **
Ni2+nickel ion Au+gold(I)
aurous
P3-phosphide
Zn2+zinc ion Au3+gold(III)
auric
As3-arsenide
Cu+copper(I)
cuprous
Cu2+copper(II)
cupric
**

Common Polyatomic Anions

Polyatomic ions consist of multiple atoms bonded together carrying a net electrical charge.

SymbolName SymbolName SymbolName
NO3-nitrate ClO4-perchlorate SO42-sulfate
NO2-nitrite ClO3-chlorate HSO4-hydrogen sulfate
CrO42-chromate ClO2-chlorite SO32-sulfite
Cr2O72-dichromate ClO-hypochlorite HSO3-hydrogen sulfite
CN-cyanide IO4-periodate C2O42-oxalate
MnO4-permanganate IO3-iodate HC2O4-hydrogen oxalate
OH-hydroxide IO-hypoiodite PO43-phosphate
O22-peroxide BrO3-bromate HPO42-hydrogen phosphate
NH2-amide BrO-hypobromite PO33-phosphite
CO32-carbonate HCO3-hydrogen carbonate H2PO4-dihydrogen phosphate

Summary of Ions, Cations and Anions

  • Cations are positively charged ions formed by loss of electrons.
  • Anions are negatively charged ions formed by gain of electrons.
  • Monoatomic ions consist of a single atom.
  • Polyatomic ions consist of multiple atoms bonded together.
  • Ions are essential in chemical reactions, electrochemistry, and materials engineering.

See Also


Links relevant to organic chemistry..
  1. Table of common cations and ions .... Short but useful list
  2. Table of common anions and cations... Useful table -site also include lots more chemical tables
  3. Names, formulas and charges of the most common ions... Another usefull table within a very comprehensive website