Roymech engineering encyclopedia

Painting and Hot-Dip Galvanizing for Corrosion Protection


Painting and hot-dip galvanizing are widely used to protect engineering components and structures from corrosion. They can also provide colour, identification, improved appearance and other surface properties.

The performance of any protective coating depends on more than the coating material itself. Surface preparation, component design, application, environment, inspection and maintenance can all influence the resulting service life.

Painting Engineering Surfaces

Paint is a liquid or otherwise applied coating material which forms a protective film on a surface. In engineering it is commonly used for corrosion protection, decoration, identification and functional surface requirements.

Industrial paints and coating materials vary considerably in composition, but important constituents can include:

  • Pigments - provide colour and opacity and may also contribute to corrosion protection and other coating properties.
  • Binders or resins - form the principal continuous film and bind the pigment and other constituents together.
  • Solvents or water - provide suitable application properties and subsequently evaporate where applicable.
  • Additives - may be included to modify properties such as flow, drying, curing, stability, wetting or resistance to particular service conditions.

The Paint Coating System

Engineering protection is normally achieved using a complete coating system rather than considering the final colour coat in isolation. Depending on the coating specification, a system can include:

  1. Surface inspection and preparation
  2. Cleaning and removal of contamination
  3. Application of a primer
  4. One or more intermediate coats where required
  5. Application of the finishing or topcoat
  6. Curing or drying
  7. Inspection of the completed coating

Not every modern coating system requires separate primer, undercoat and topcoat layers. The number and type of coats depend on the coating technology, substrate, environment and required performance.

Surface Preparation Before Painting

Surface preparation is one of the most important stages in achieving a durable protective coating.

Depending on the substrate and coating system, preparation may involve:

  • Removal of oil and grease
  • Removal of dirt and other contamination
  • Removal of rust and corrosion products
  • Removal of loose or defective existing coatings
  • Removal of mill scale where required
  • Abrasive blast cleaning
  • Mechanical cleaning
  • Chemical treatment
  • Producing an appropriate surface profile for coating adhesion

The required preparation should be established from the coating specification and the condition of the substrate rather than assuming that one preparation method is suitable for every coating.

Primers

A primer is the first coat in many protective paint systems and is applied directly to the prepared substrate.

Depending on the particular coating system, a primer can provide:

  • Adhesion to the substrate
  • Corrosion protection
  • A suitable surface for subsequent coating layers
  • Sealing or stabilisation of the prepared surface

The appropriate primer depends on the substrate, environmental exposure and subsequent coating layers.

Intermediate Coats

Intermediate coats may be used between the primer and finishing coat to build the required coating thickness and provide additional barrier protection.

The term undercoat is commonly encountered in traditional paint systems, but modern industrial protective-coating specifications more often define the individual coats by their coating type, function and required film thickness.

Topcoats

The topcoat forms the outer surface of the paint system and is directly exposed to the service environment.

Depending on the application, the topcoat may be selected to provide:

  • Weather resistance
  • Colour and appearance
  • Resistance to ultraviolet exposure
  • Chemical resistance
  • Ease of cleaning
  • Abrasion or wear resistance
  • Identification or safety marking

Water-Based and Solvent-Based Coatings

Paints can use different carrier systems. Two broad categories are water-based and solvent-based coatings.

In a solvent-based coating, organic solvents may be used to provide the viscosity and application characteristics required. Solvent subsequently evaporates as the coating dries or cures.

Water-based coatings use water as an important part of the liquid carrier. These include polymer dispersions and other coating chemistries designed for aqueous application.

The fact that a coating is described as water-based or solvent-based does not by itself define its complete curing mechanism or engineering performance. The binder chemistry and complete coating formulation must also be considered.

Drying and Curing

Paint coatings do not all form their final film by the same mechanism. Depending on the coating, film formation can involve:

  • Evaporation of solvent or water
  • Coalescence of polymer particles
  • Oxidative reaction
  • Chemical reaction between coating components
  • Heat-assisted curing
  • Other coating-specific curing mechanisms

Some production coating systems are heated or stoved to accelerate or complete curing. The required temperature and time depend on the particular coating specification.

Lacquers

The term lacquer has traditionally been used for coatings which form a film principally through evaporation of volatile solvent, leaving the film-forming material behind.

Modern coating terminology and chemistry are more varied, so the actual product specification should be used when determining the drying or curing mechanism of a particular coating.

Coating Thickness

Protective coating specifications commonly define the required film thickness. Insufficient thickness may reduce protective performance, while excessive coating thickness can also create problems depending on the coating system.

Coating thickness should therefore be controlled and inspected in accordance with the applicable coating specification and measurement procedure.

Painting Component Design Considerations

Component geometry can have a significant effect on coating quality. Designers should consider whether surfaces can be adequately prepared, coated, inspected and maintained.

Potential problem areas include:

  • Sharp edges
  • Crevices
  • Overlapping surfaces
  • Inaccessible recesses
  • Water traps
  • Poor drainage
  • Areas difficult to inspect
  • Features which make surface preparation difficult

Where corrosion protection is important, coating access should be considered during component design rather than after fabrication is complete.

Hot-Dip Galvanizing

Hot-dip galvanizing protects iron and steel by immersing the prepared component in molten zinc. The zinc reacts metallurgically with the iron in the steel to produce a series of zinc-iron intermetallic layers, normally with a zinc-rich outer layer.

The resulting coating provides both a physical barrier between the steel and its environment and sacrificial protection. Zinc is anodic relative to steel and can therefore provide protection to small areas of exposed steel adjacent to the zinc coating.

Hot-Dip Galvanizing Process

The precise plant process varies, but batch hot-dip galvanizing generally includes the following principal stages:

  1. Degreasing / cleaning
    Oil, grease, dirt and other suitable organic contaminants are removed. Materials which cannot be removed chemically may require mechanical removal before galvanizing.
  2. Chemical cleaning / pickling
    Rust, iron oxides and mill scale are removed, commonly using an acidic cleaning process. Abrasive cleaning may also be used where appropriate.
  3. Fluxing
    The prepared steel is treated with a flux which removes remaining oxides and helps prevent further oxidation before immersion in the zinc bath.
  4. Immersion in molten zinc
    The prepared component is completely immersed in molten zinc. A typical hot-dip galvanizing bath operates at approximately 450°C.
  5. Coating formation
    Iron in the steel reacts with the molten zinc to form zinc-iron intermetallic layers.
  6. Withdrawal and draining
    The component is withdrawn from the bath and excess zinc is allowed to drain from the surfaces.
  7. Cooling and inspection
    The completed coating is cooled and inspected for the required coating condition and specification.

How Galvanizing Protects Steel

A hot-dip galvanized coating protects steel in two important ways.

Barrier Protection

The zinc coating physically separates the underlying steel from the corrosive environment.

Sacrificial Protection

Zinc is anodic to steel. Where a small area of steel becomes exposed adjacent to the coating, the surrounding zinc can corrode preferentially and provide cathodic protection to the exposed steel.

Galvanizing and Component Design

A component intended for hot-dip galvanizing should be designed with the galvanizing process in mind. The complete fabricated component must be handled, cleaned, immersed in molten zinc, withdrawn and drained.

Important considerations include:

  • Component size relative to the galvanizing facility
  • Handling and lifting arrangements
  • Ventilation of enclosed or hollow sections
  • Drainage of cleaning solutions and molten zinc
  • Avoidance of sealed cavities
  • Overlapping and contacting surfaces
  • Weld quality and removal of unsuitable contamination
  • Distortion of fabricated assemblies
  • Required coating appearance
  • Subsequent assembly and dimensional requirements

Venting and Drainage

Cleaning solutions, flux and molten zinc must be able to enter and leave the appropriate parts of a fabricated component. Air and gases must also be able to escape as the component is immersed.

Poor venting or drainage can result in uncoated areas, trapped process fluids, excessive zinc accumulation and serious process hazards.

Vent and drain arrangements should therefore be agreed with the galvanizer when designing hollow or complex fabrications.

Galvanizing and Distortion

Fabricated steelwork can contain residual stresses from rolling, forming, welding and other manufacturing operations. Heating the complete assembly during hot-dip galvanizing can allow distortion to occur in susceptible fabrications.

The risk depends on component geometry, material thickness, fabrication sequence, weld arrangement and structural stiffness. Large thin plates, asymmetric assemblies and heavily welded structures can require particular attention.

Threads and Fits After Galvanizing

The zinc coating adds material to the surface and can therefore affect threads, holes, fits and other close-clearance features.

Components requiring galvanizing should be detailed with the intended coating process in mind. Thread allowances and mating components should follow the relevant fastener and galvanizing requirements rather than assuming that an uncoated fit will remain unchanged after coating.

Painting Galvanized Steel

Galvanized steel can also be painted or powder coated where additional corrosion protection, colour or appearance is required. A combined galvanized and organic coating system is often referred to as a duplex system.

Painting galvanized steel requires appropriate surface preparation and a coating system compatible with the zinc surface. The condition and age of the galvanized surface can influence the preparation required.

Painting or Hot-Dip Galvanizing?

The most appropriate corrosion-protection system depends on the component and its operating environment.

Consideration Paint coating Hot-dip galvanizing
Colour Very wide range of colours and finishes available. Natural zinc appearance unless subsequently painted or otherwise finished.
Application Can be applied to components and structures using several different application methods. Fabricated component must be suitable for immersion in the galvanizing process.
Protection mechanism Principally depends on the particular coating system providing protection to the substrate. Provides barrier protection together with sacrificial protection from zinc.
Surface preparation Preparation depends on substrate and specified coating system. Cleaning, chemical preparation and fluxing form part of the hot-dip galvanizing process.
Component geometry Access for preparation and coating is important. Immersion, venting, drainage, handling and bath capacity must be considered.
Maintenance Inspection and maintenance requirements depend on coating and environment. Can provide long-term protection, but coating condition should still be considered throughout service.

Corrosion Environment

The required protection cannot be selected solely from the name of the coating. Corrosion severity depends on the actual service environment.

Factors can include:

  • Indoor or outdoor exposure
  • Moisture and time of wetness
  • Atmospheric contaminants
  • Marine exposure
  • Industrial atmosphere
  • Chemical exposure
  • Temperature
  • Immersion or soil contact
  • Mechanical wear and damage
  • Required design life

A coating system should therefore be selected against a defined service environment and required performance rather than simply specifying "painted" or "galvanized" on an engineering drawing.

Inspection and Maintenance

Protective coatings should be inspected where their condition is important to the integrity or service life of the component.

Inspection can consider:

  • Surface preparation before coating
  • Coating continuity
  • Required coating thickness
  • Adhesion where applicable
  • Visible coating defects
  • Damage during handling or assembly
  • Corrosion developing during service

The appropriate inspection method and acceptance criteria should come from the applicable coating specification rather than from a general visual assessment alone.

Designing for Corrosion Protection

Corrosion protection is most effective when considered during the design of the component rather than added after the geometry and fabrication method have already been fixed.

Good engineering design should consider:

  • Avoiding water and contaminant traps
  • Providing drainage
  • Avoiding inaccessible corrosion-prone crevices where practical
  • Providing access for surface preparation
  • Providing access for coating and inspection
  • Considering coating thickness when specifying fits and threads
  • Allowing for maintenance where required
  • Selecting compatible materials and coatings
  • Considering fabrication and welding before coating
  • Considering the complete expected service environment

Related Manufacturing Processes

Further Engineering Resources

The following external resources were included on the original RoyMech page and are retained for further information and subsequent link review.

  1. American Galvanizers Association
    Technical information relating to hot-dip galvanizing and galvanized steel.
  2. PaintQuality.com
    Legacy paint information resource retained from the original RoyMech page.
  3. General Paint
    Legacy paint resource retained from the original RoyMech page.
  4. Design InSite
    Legacy manufacturing and surface-process resource retained from the original RoyMech page.
  5. Institute of Materials, Minerals & Mining - Vitreous Enamel
    Resource relating to vitreous enamel and surface finishing.
  6. Industrial Galvanizers Corporation
    Legacy galvanizing technical resource retained from the original RoyMech page.