Roymech engineering encyclopedia

Chemical Resistance of Stainless Steels and Nickel Alloys


This corrosion resistance table provides a preliminary comparison of 304, 321, 347, 316 and 316L stainless steels, nickel, Monel, Inconel and Hastelloy C when exposed to a wide range of chemicals and operating temperatures.

Engineers and students can use the table to compare how different corrosion-resistant alloys may perform in a particular chemical environment. Find the chemical or process fluid in the first column, check the operating temperature, and then compare the resistance ratings across the available materials.

How to Use the Corrosion Resistance Table

  1. Find the chemical or process fluid in the first column.
  2. Check the concentration and temperature shown for that condition.
  3. Compare the A to E corrosion-resistance ratings for each alloy.
  4. Use the results to identify materials that may warrant further investigation.

The ratings are intended as preliminary engineering guidance rather than a final material-selection specification. Actual corrosion performance can also be affected by concentration, temperature, contamination, aeration, flow conditions, fabrication, welding and other service conditions.

The table below provides approximate corrosion resistance data for selected corrosion-resistant metals exposed to a range of common chemicals and operating conditions. The information has been collated from a number of engineering reference sources and is intended for preliminary material comparison and guidance.

Corrosion performance can vary significantly with chemical concentration, temperature, contamination, flow conditions and other service factors. For critical applications, material selection should be confirmed using current manufacturer data, recognised engineering references or appropriate corrosion testing.


Key to Letters designating corrosion resistance

  • A...Excellent Good Resistance less than 0,01mm per month (0,1 mm per year)
  • B...Good Resistance < 0,01mm to 0,1mm per month (0,1mm to 1mm per year)
  • C...Fair Resistance 0,1mm to 0,25mm per month ( 1mm to 3mm per year)
  • D...Some Resistance 0,25mm to 0,9mm per month (3mm -11 mm per year)
  • E...No Resistance > 0,9 mm per month (11 mm per year)
Chemical /condition Temp
oC
304, 321,347
Stain. Stl.
316,316L
Stain. Stl.
Nickel Monel Iconel Hastalloy C
Acetic Acid (20%) 21 A A A A A A
Acetic Acid (50%) 21 A A B A A A
Acetic Acid (50%) Boiling C B B A B A
Acetic Acid (80%) 21 A A B A A A
Acetic Acid (80%) Boiling D B B A B A
Acetic Acid (100%) 21 A A A A A A
Acetic Acid (100%) Boiling C B C B B A
Acetic Acid (100% - 150 lb pressure) 204 E C - - - A
Acetic Anhydride Boiling A A A A A A
Acetic Anhydride 21 A A A A A A
Acetic Vapours (100%) Hot E C C B B  
Acetic Vapours (30%) Hot C B - - -  
Acetone Boiling A A A A A A
Acetone 21 A A A A A  
Alcohol Ethyl 21 A A A A A A
Alcohol Ethyl Boiling A A A A A A
Alcohol Methyl 21 A A A A A A
Alcohol Methyl 66 C B A A A A
Aluminium Acetate - saturated   A A - - -  
Aluminium Chloride 21 D C B B C A
Alum (Chrome) 5% 21 A A C C A  
Aluminium Fluoride 21 D C A A B B
Aluminium Hydroxide - saturated   A A A A A B
Aluminium Molten E E E E E  
Aluminium Potassium Sulphate (2% alum) 21 A A A A A C
Aluminium Potassium Sulphate (10%) 21 A A A A A C
Aluminium Potassium Sulphate (10%) Boiling B A B A B C
Aluminium Potassium Sulphate (saturated) Boiling C B C B B C
Aluminium Sulphate (10%) 21 A A A A A B
Aluminium Sulphate (10%) Boiling B A B A B B
Aluminium Sulphate (saturated) 21 A A A A A B
Aluminium Sulphate (saturated) Boiling B A B A B B
Ammonia - all concentrations 21 A A - - A A
Ammonia - gas Hot D - - - - A
Ammonia Liquor 21 A A C C A A
Ammonia Liquor Boiling A A C C A A
Ammonium Bicarbonate 21 A A A A A  
Ammonium Bicarbonate Hot A A A A A  
Ammonium Carbonate (1% & 5%) 21 A A A A A B
Ammonium Chloride (1%) 21 A A A A A D
Ammonium Chloride (10% solution) Boiling A A A A B D
Ammonium Chloride (28% solution) Boiling B A A A B D
Ammonium Chloride (50% solution) Boiling B A A A B D
Ammonium Nitrate (All con. agitated) 21 A A C C A B
Ammonium Nitrate (All con. aerated) 21 A A C C A B
Ammonium Nitrate (saturated) Boiling A A E E B B
Ammonium Oxalate (5%) 21 A A A A A A
Ammonium Persulphate (5%) 21 A A E E A B
Ammonium Phosphate (5%) 21 A A A A A B
Ammonium Sulphate (1% & 5% agitated) 21 A A A A A B
Ammonium Sulphate (1% & 5% aerated) 21 A A A A A B
Ammonium Sulphate (10%) Boiling B A B A B B
Ammonium Sulphate (saturated) Boiling B A B A B B
Ammonium Sulphite Cold A A C B B  
Ammonium Sulphite Boiling A A E C C  
Aniline (3%) 21 A A A A A B
Aniline (conc. Crude) 21 A A A A A B
Aniline Hydrochloride 21 E D B B C D
Antimony Trichloride 21 E D A A A  
Barium Carbonate 21 A A A A A B
Barium Chloride (5%) 21 A A A A A B
Barium Chloride (saturated) 21 A A A A A  
Barium Chloride (aqueous solution) Hot B A A A B  
Barium Nitrate (aqueous solution) Hot A A C C B  
Barium Sulphate Barytes (blanc * * *ixe) 21 A A A A A A
Benzene 21 A A A A A B
Benzoic Acid 21 A A A A A B
Boracic Acid (5%) Hot/Cold A A A A A  
Borax (5%) Hot A A A A A B
Bromide (dry) 21 - - A A A  
Bromine Water 21 E D D D D A
Butyric Acid (5%) 21 A A A A A A
Butyric Acid (5%) 66 A A A A A A
Butyric Acid (aqueous solution - sp. g. 0.964) Boiling A A - - A A
Calcium Carbonate 21 A A A A A B
Calcium Chlorate (dilute solution) 21 A A A A A  
Calcium Chlorate (dilute solution) Hot A A A A B  
Calcium Chloride (dilute solution) 21 B A A A A A
Calcium Chloride (concentrated solutions) 21 B A A A A A
Calcium Hydroxide (10%) Boiling A A A A A A
Calcium Hydroxide (20%) Boiling A A A A A A
Calcium Hydroxide (50%) Boiling C B A A A A
Calcium Hyperchlorite (2%) 21 B A C C B B
Calcium Sulphate (saturated) 21 A A A A A B
Carbolic Acid (Phenol) Boiling A A A A A A
Carbonated water   A A A A A  
Carbon Bisulphide 21 A A A A A  
Carbon monoxide gas 871 A A - - - B
Carbon monoxide gas 760 A A - - - B
Carbon tetrachloride (pure) 21 A A A A A A
Carbon tetrachloride (aqueous solution - 5-10%) 21 C - A A A  
Chloracetic Acid 21 D C A A A A
Chlorbenzol Conc. (pure) 21 A A A A A  
Chloric Acid 21 E D D D D A
Chlorinated Water (saturated) 21 C B C C B A
Chlorine gas (dry) 21 C B C C C A
Chlorine gas (moist) 21 D C C C C A
Chlorine gas 100 E D A A A  
Chloroform 21 A A A A A A
Chromic Acid (5%) 21 A A A A A B
Chromic Acid (10% CP) Boiling C B C B C A
Chromic Acid (50% Com. Cont. SO3 Boiling D C - - - B
Chromium Plating Bath 21 A A C C A  
Citric Acid (5% still) 21 A A A A A A
Citric Acid (5% still) 66 A A A A A A
Citric Acid (15%) 21 A A A A A A
Citric Acid (15%) Boiling B A B A A A
Citric Acid (concentrated) Boiling C B B A B A
Copper Acetate (saturated sol.) 21 A A C C A  
Copper Carbonate (sat. solution in 50% NH_OH)   A A C C A  
Copper Chloride (1% agitated) 21 B A B B A  
Copper Chloride (1% aerated) 21 B A B B A  
Copper Chloride (5% agitated) 21 C B C C C  
Copper Chloride (5% aerated) 21 E D D D C  
Copper Cyanide (saturated solution) Boiling A A B B B A
Copper Nitrate (1% and 5%) 21 A A C C A B
Copper Nitrate (50% aqueous solution) Hot A A E E C B
Copper Sulphate (5%) 21 A A B B A A
Copper Sulphate (saturated solution) Boiling A A C C C A
Creosote (Coal Tar) Hot A A A A A A
Creosote Oil Hot A A A A A  
Cyanogen Gas 21 A A A A A  
Dinitrochlorbenzol (melted and solidified) 21 A A - - -  
Ether 21 A A A A A B
Ethyl Chloride 21 A A A A A B
Ethylene Chloride 21 A A A A A  
Ferric Chloride (1% solution - still) 21 B A B C C B
Ferric Chloride (1% solution - still) Boiling D C E E E B
Ferric Chloride (5% solution - still) 21 D C D D C B
Ferric Chloride (5% - agitated) 21 C C D D C B
Ferric Chloride (5% - aerated) 21 C C D D C B
Ferric Hydroxide (Hydrated Iron Oxide) 21 A A A A A  
Ferric Nitrate (1% and 5%) 21 A A D D A B
Ferric Sulphate (1% and 5%) 21 A A C C A A
Ferrous Sulphate (dilute sol.) 21 A A A A A B
Fluorine 21 E E A A A B
Formalin (40% sol. Formaldehyde)   A A A A A  
Formic Acid (5% still) 21 B A A A A A
Formic Acid (5% still) 66 B A A A A A
Fuel Oil Hot A A B B A A
Fuel Oil (containing sulphuric acid)   C B B B B A
Gallic Acid (5% solution) 21 A A A A A B
Gallic Acid (5% solution) 66 A A A A A B
Glue (dry) 21 A A A A A  
Glue (solution - acid) 21 B A A A A  
Glue (solution - acid) 60 B A A A A  
Glycerine 21 A A A A A A
Hydrochloric Acid (all concentrations) 21 E E B B C A/B
Hydrocyanic Acid   A A A A A A
Hydrofluosilicic Acid 21 E D A A B B
Hydrogen Peroxide 21 A A A A A A
Hydrogen Peroxide Boiling B A - - - A
Hydrogen Sulphide (dry)   A A A A A A
Hydrogen Sulphide (wet_   B A A A A A
Hyposulphite Soda (Hypo)   A A B A A  
Iodine   E D D D D A
Iodoform   A A - - - D
Lactic Acid (5%) 21 A A A A A B
Lactic Acid (5%) 66 B A A A A B
Lactic Acid (10%) Boiling D B C C B B
Lactic Acid (10%) 66 C B B B B B
Lead Molten B B D D B  
Linseed Oil 21 A A A A A  
Magnesium Chloride (1% and 5% - still) 21 A A A A A A
Magnesium Chloride (1% and 5% - still) Hot C B A A A A
Magnesium Sulphate Hot/Cold A A A A A B
Malic Acid Hot/Cold B A A A A B
Mayonnaise 21 A A A A A A
Mercuric Chloride (dilute solutions   E D D D D C
Mercury   A A A A A A
Methanol (Methyl Alcohol) 21 A A A A A A
Mixed Acids (53% H2SO4) Cold A A D D A  
Mixed Acids (45% HN03) Cold A A D D A  
Molasses   A A A A A A
Muriatic Acid 21 E E B B C  
Mustard 21 A A A B B A
Naphtha 21 A A A A A B
Naphtha (crude) 21 A A A A A B
Nickel Chloride (solution) 21 A A B B B B
Nickel Sulphate Hot/Cold A A A A A B
Niter Cake Fused B A - - -  
Nitric Acid (5% solution) 21 A A E E B A
Nitric Acid (20% solution) 21 A A E E A A
Nitric Acid (50% solution) 21 A A E E A A
Nitric Acid (50% solution) Boiling A A E E C A
Nitric Acid (65% solution) Boiling B B E E D A
Nitric Acid (concentrated) 21 A A E E A B
Nitric Acid (concentrated) Boiling D D E E D B
Nitrous Acid (5% solution) 21 A A D D A D
Oils (crude) Hot/Cold A A A A A  
Oils (vegetable, mineral) Hot/Cold A A A A A  
Oleic Acid 21 A A A A A A
Oxalic Acid (5%) Hot/Cold A A A A A B
Oxalic Acid (10%) 21 A A A A A B
Oxalic Acid (10%) Boiling B C B A B B
Paraffin Hot/Cold A A A A A B
Petroleum Ether   A A A A A  
Phenol   A A A A A A
Phosphoric Acid (1%) 21 A A A A A A
Phosphoric Acid (5%) 21 A A A A A A
Phosphoric Acid (10% - still) 21 C A B A A A
Phosphoric Acid (10% - agitated) 21 C B B B B A
Phosphoric Acid (10% - aerated) 21 C B C C B A
Picric Acid 21 A A - - - B
Potassium Bichromate 21 A A A A A  
Potassium Bromide 21 B A A A A B
Potassium Carbonate (1%) 21 A A A A A B
Potassium Carbonate (1%) Hot A A A A A B
Potassium Chlorate   A A A A A B
Potassium Chloride (1% and 5%) 21 A A A A A A
Potassium Chloride (1% and 5%) Boiling A A A A A A
Potassium Ferricyanide (5%) 21 A A - - - B
Potassium Ferrocyanide (5%) 21 A A - - - B
Potassium Hydroxide (5%) 21 A A A A A B
Potassium Hydroxide (27%) Boiling A A A A A B
Potassium Hydroxide (50%) Boiling B A A A A B
Potassium Nitrate (1% and 5%) 21 A A A A A B
Potassium Nitrate (1% and 5%) Hot A A A A A B
Potassium Oxalate   A A A A A A
Potassium Permanganate (5%) 21 A A A A A A
Potassium Sulphate (1% and 5%) 21 A A A A A B
Potassium Sulphate (1% and 5%) Hot A A A A A B
Potassium Sulphide (salt)   A A A A A  
Pyrogallic Acid   A A A A A  
Quinine Bisulphate (dry)   B A A A A  
Quinine Sulphate (dry)   A A A A A  
Rosin Molten A A A A A  
Sea Water   A A A A A A
Sewage   A A A A A  
Silver Bromide   B A - - - A
Silver Chloride   E E - - -  
Silver Nitrate   A A E E A A
Soap 21 A A A A A A
Sodium Acetate (moist)   A A A A A A
Sodium Bicarbonate (all concentrations) 21 A A A A A B
Sodim Bicarbonate (5% - still) 66 A A A A A B
Sodium Carbonate (5%) 21 A A A A A A
Sodium Carbonate (5%) 66 A A A A A A
Sodium Chloride (5% - still) 21 A A A A A A
Sodium Chloride (5% - still) 66 A A A A A A
Sodium Chloride (20% aerated) 21 A A A A A A
Sodium Chloride (saturated) 21 A A A A A A
Sodium Chloride (saturated) Boiling B A A A A A
Sodium Fluoride (5% solution)   B A A A A A
Sodium Hydroxide   A A A A A  
Sodium Hypochlorite (5% - still)   B A C C C A
Sodium Hyposulphite 21 A A A A A  
Sodium Nitrate Fused C B A B A B
Sodium Sulphate (5% -still) 21 A A A A A B
Sodium Sulphate (all concentrations) 21 A A A A A B
Sodium Sulphide (saturated)   B A A A A B
Sodium Sulphite (5%) 21 A A A A A B
Sodium Sulphite (10%) 66 A A A A A B
Stannic Chloride (Sp. G. 1.21) Boiling E E B B C  
Stannic Chloride (solution) 21 D C A B B  
Stannous Chloride (saturated)   C A A B B  
Stearic Acid   A A A A A  
Sulphur Chloride   E D A A A  
Sulphur Dioxide Gas (moist) 21 B A D C C  
Sulphur Dioxide Gas (moist) 302 A A - - -  
Sulphur (dry) Molten A A A A A  
Sulphur (wet)   B A B B A  
Sulphuric Acid (5%) 21 C B A A A B
Sulphuric Acid (5%) Boiling E C D A C B
Sulphuric Acid (10%) 21 C B B A B B
Sulphuric Acid (10%) Boiling E D C A C B
Sulphuric Acid (50%) 21 D C B A B B
Sulphuric Acid (50%) Boiling E D E E E B
Sulphuric Acid (concentrated) 21 A A B B B A
Sulphuric Acid (concentrated) Boiling D D E E E A
Sulphuric Acid (concentrated) 149 E E E E E A
Sulphuric Acid (fuming) 21 C B C B B B
Sulphurous Acid (saturated) 21 C B E E E B
Sulphurous Acid (saturated 60 lb pressure) 121 C B E E E B
Sulphurous Acid (saturated 70 - 125 lb pressure) 154 C B E E E B
Sulphurous Acid (150 lb pressure) 191 C B E E E B
Sulphurous Acid (sulphurous spray) 21 D D E E E B
Tannic Acid 21 A A A A A B
Tannic Acid 66 B A A A A B
Tartaric Acid 21 A A A A A B
Tartaric Acid 66 B A A A A B
Tin Molten C C E E E C
Trichloracetic Acid 21 E E B B B B
Varnish 21 A A A A A A
Varnish Hot A A A A A A
Vinegar Fumes   B A B A A A
Vinegar (still) 21 A A A A A A
Vinegar (agitated)   A A A A A A
Vinegar (aerated) 21 A A B A A A
Zinc Molten E E E E E  
Zinc Chloride (5% - still) 21 A A A A A B
Zinc Chloride (5% - still) Boiling B B B B B B
Zinc Sulphate (5%) 21 A A A A A A
Zinc Sulphate (saturated) 21 A A A A A A
Zinc Sulphate (25%) Boiling A A A A A A
Chemical /condition Temp
oC
304, 321,347
Stain. Stl.
316,316L
Stain. Stl.
Nickel Monel Iconel Hastalloy C

Using Corrosion Resistance Data for Material Selection

This table is most useful during the preliminary stages of material selection. An engineer can identify the chemical, concentration and operating temperature, then compare the corrosion resistance ratings of the available stainless steels and nickel alloys.

A favourable corrosion resistance rating does not automatically make a material suitable for the complete engineering application. Mechanical strength, operating temperature, pressure, fabrication and welding requirements, availability and cost may also influence the final material choice.

Particular care should be taken where operating conditions differ from those shown in the table. Changes in chemical concentration or temperature can significantly affect corrosion behaviour, so final material selection for critical applications should be confirmed using appropriate manufacturer or specialist corrosion data.


Frequently Asked Questions

How do I use the stainless steel and nickel alloy corrosion resistance table?

Find the chemical or process fluid in the table, check the concentration and operating temperature, and then compare the corrosion resistance ratings for the available stainless steels and nickel alloys. The table is intended to help identify materials that may be suitable for further investigation.

What do the A to E corrosion resistance ratings mean?

The A to E ratings indicate the approximate corrosion resistance of each material under the conditions shown in the table. Lower corrosion rates receive the better ratings, while the poorer ratings indicate progressively greater material attack. Always refer to the rating key provided with the table when interpreting the results.

Why are chemical concentration and temperature important when selecting a corrosion-resistant alloy?

Corrosion behaviour can change significantly with chemical concentration and temperature. A material that performs well under one set of conditions may have substantially different corrosion resistance at another concentration or operating temperature.

Can I use this table to choose between 304 and 316 stainless steel?

The table can be used to compare the approximate corrosion resistance of the stainless steel grades shown for particular chemicals and operating conditions. However, corrosion resistance is only one part of material selection, and factors such as mechanical properties, fabrication, welding, temperature and cost should also be considered.

Can the corrosion resistance table be used for final material selection?

The table is intended for preliminary engineering comparison and should not be the sole basis for final material selection. For critical applications, the selected alloy should be checked using current manufacturer data, recognised engineering references or appropriate corrosion testing for the actual operating conditions.

Related Corrosion Links



Links to Corrosion Resistance Tables
  1. Corrosion Doctors ...An excellent reference site for the very important topic of corrosion
  2. Omega...Chemical Chart-Some Plastics
  3. dultmeier...Relatively extensive Chemical Chart
  4. Chemical Compatibility ...Cole Porter ..American site with very clear information on chemical compatibility